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Episode 233

Muramasa appears before Ichigo and explains how he freed the Zanpakuto from the Soul Reapers, as well as gave them a physical form to exist. Muramasa then attacks, and during the course of the battle, Zangetsu is freed from Ichigo. Unable to use his Zanpakuto, Ichigo falls before Zangetsu's Getsugatensho.

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Season 1

EP 357

Episode 357

Orihime and Chad exchange what information they have about Tsukishima to figure out what he has done to the both of them.